GEOTRACES IC1 (BATS) contamination‐prone trace element isotopes Cd, Fe, Pb, Zn, Cu, and Mo intercalibration
Identifieur interne : 005675 ( Main/Exploration ); précédent : 005674; suivant : 005676GEOTRACES IC1 (BATS) contamination‐prone trace element isotopes Cd, Fe, Pb, Zn, Cu, and Mo intercalibration
Auteurs : Edward A. Boyle [États-Unis] ; Seth John [États-Unis] ; Wafa Abouchami [Allemagne] ; Jess F. Adkins [États-Unis] ; Yolanda Echegoyen-Sanz [États-Unis] ; Michael Ellwood [Australie] ; A. Russell Flegal [États-Unis] ; Kyrstin Fornace [États-Unis] ; Celine Gallon [États-Unis] ; Steve Galer [Allemagne] ; Melanie Gault-Ringold [Nouvelle-Zélande] ; Francois Lacan [France] ; Amandine Radic [France] ; Mark Rehkamper [Royaume-Uni] ; Olivier Rouxel [États-Unis, France] ; Yoshiki Sohrin [Japon] ; Claudine Stirling [Nouvelle-Zélande] ; Claire Thompson [Australie] ; Derek Vance [Royaume-Uni] ; Zichen Xue [Royaume-Uni] ; Ye Zhao [Royaume-Uni]Source :
- Limnology and Oceanography: Methods [ 1541-5856 ] ; 2012-09.
Descripteurs français
- Wicri :
- topic : Cadmium.
English descriptors
- KwdEn :
- Abouchami, Acta, Adkins, Anal, Anion, Boyle, Cadmium, Chem, Coprecipitation, Coprecipitation method, Cosmochim, Deep water, Double spike, Earth planet, Fractionation, Geochim, Geoff smith, Geotraces, Gpri, Intercalibration, Iron isotopes, Isobaric interferences, Isotope, Isotope analysis, Isotope compositions, Isotope data, Isotope fractionation, Isotope ratios, Isotopic, Isotopic composition, Mainz, Mass bias, Minimum amount, Nist, Otago, Permil, Report data, Ripperger, Sample depth, Seawater, Seawater samples, Seth john, Single analysis, Spike, Standard error, Trace element isotopes, Trace element isotopes table, Trace metals.
- Teeft :
- Abouchami, Acta, Adkins, Anal, Anion, Boyle, Cadmium, Chem, Coprecipitation, Coprecipitation method, Cosmochim, Deep water, Double spike, Earth planet, Fractionation, Geochim, Geoff smith, Geotraces, Gpri, Intercalibration, Iron isotopes, Isobaric interferences, Isotope, Isotope analysis, Isotope compositions, Isotope data, Isotope fractionation, Isotope ratios, Isotopic, Isotopic composition, Mainz, Mass bias, Minimum amount, Nist, Otago, Permil, Report data, Ripperger, Sample depth, Seawater, Seawater samples, Seth john, Single analysis, Spike, Standard error, Trace element isotopes, Trace element isotopes table, Trace metals.
Abstract
We report data on the isotopic composition of cadmium, copper, iron, lead, zinc, and molybdenum at the GEOTRACES IC1 BATS Atlantic intercalibration station. In general, the between lab and within‐lab precisions are adequate to resolve global gradients and vertical gradients at this station for Cd, Fe, Pb, and Zn. Cd and Zn isotopes show clear variations in the upper water column and more subtle variations in the deep water; these variations are attributable, in part, to progressive mass fractionation of isotopes by Rayleigh distillation from biogenic uptake and/or adsorption. Fe isotope variability is attributed to heavier crustal dust and hydrothermal sources and light Fe from reducing sediments. Pb isotope variability results from temporal changes in anthropogenic source isotopic compositions and the relative contributions of U.S. and European Pb sources. Cu and Mo isotope variability is more subtle and close to analytical precision. Although the present situation is adequate for proceeding with GEOTRACES, it should be possible to improve the within‐lab and between‐lab precisions for some of these properties.
Url:
DOI: 10.4319/lom.2012.10.653
Affiliations:
- Allemagne, Australie, France, Japon, Nouvelle-Zélande, Royaume-Uni, États-Unis
- Californie, Caroline du Sud, Massachusetts, Midi-Pyrénées, Occitanie (région administrative), Région du Kansai
- Kyoto, Toulouse
- Université de Kyoto
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Le document en format XML
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Boyle</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, E25‐619, E25‐619, Cambridge, MA 02139</wicri:regionArea><placeName><region type="state">Massachusetts</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation></author><author><name sortKey="John, Seth" sort="John, Seth" uniqKey="John S" first="Seth" last="John">Seth John</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125</wicri:regionArea><placeName><region type="state">Californie</region></placeName></affiliation><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Earth and Ocean Sciences, University of South Carolina, Columbia, SC 29208</wicri:regionArea><placeName><region type="state">Caroline du Sud</region></placeName></affiliation></author><author><name sortKey="Abouchami, Wafa" sort="Abouchami, Wafa" uniqKey="Abouchami W" first="Wafa" last="Abouchami">Wafa Abouchami</name><affiliation wicri:level="1"><country xml:lang="fr">Allemagne</country><wicri:regionArea>Max Planck‐Institute for Chemistry, Mainz, P.O. Box 3060, 55020 Mainz</wicri:regionArea><wicri:noRegion>55020 Mainz</wicri:noRegion><wicri:noRegion>55020 Mainz</wicri:noRegion></affiliation></author><author><name sortKey="Adkins, Jess F" sort="Adkins, Jess F" uniqKey="Adkins J" first="Jess F." last="Adkins">Jess F. 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Russell" last="Flegal">A. Russell Flegal</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Institute of Marine Sciences, University of California, Santa Cruz, CA 95064</wicri:regionArea><placeName><region type="state">Californie</region></placeName></affiliation></author><author><name sortKey="Fornace, Kyrstin" sort="Fornace, Kyrstin" uniqKey="Fornace K" first="Kyrstin" last="Fornace">Kyrstin Fornace</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, E25‐619, E25‐619, Cambridge, MA 02139</wicri:regionArea><placeName><region type="state">Massachusetts</region></placeName></affiliation></author><author><name sortKey="Gallon, Celine" sort="Gallon, Celine" uniqKey="Gallon C" first="Celine" last="Gallon">Celine Gallon</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Institute of Marine Sciences, University of California, Santa Cruz, CA 95064</wicri:regionArea><placeName><region type="state">Californie</region></placeName></affiliation></author><author><name sortKey="Galer, Steve" sort="Galer, Steve" uniqKey="Galer S" first="Steve" last="Galer">Steve Galer</name><affiliation wicri:level="1"><country xml:lang="fr">Allemagne</country><wicri:regionArea>Max Planck‐Institute for Chemistry, Mainz, P.O. Box 3060, 55020 Mainz</wicri:regionArea><wicri:noRegion>55020 Mainz</wicri:noRegion><wicri:noRegion>55020 Mainz</wicri:noRegion></affiliation></author><author><name sortKey="Gault Ingold, Melanie" sort="Gault Ingold, Melanie" uniqKey="Gault Ingold M" first="Melanie" last="Gault-Ringold">Melanie Gault-Ringold</name><affiliation wicri:level="1"><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry, University of Otago, Dunedin 9054</wicri:regionArea><wicri:noRegion>Dunedin 9054</wicri:noRegion></affiliation></author><author><name sortKey="Lacan, Francois" sort="Lacan, Francois" uniqKey="Lacan F" first="Francois" last="Lacan">Francois Lacan</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire d'Etude en Géophysique et Océanographie Spatiales (LEGOS, CNES/CNRS/IRD/University of Toulouse), 14 av. Edouard Belin, 31400 Toulouse</wicri:regionArea><placeName><region type="region" nuts="2">Occitanie (région administrative)</region><region type="old region" nuts="2">Midi-Pyrénées</region><settlement type="city">Toulouse</settlement></placeName></affiliation></author><author><name sortKey="Radic, Amandine" sort="Radic, Amandine" uniqKey="Radic A" first="Amandine" last="Radic">Amandine Radic</name><affiliation wicri:level="1"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire d'Etude en Géophysique et Océanographie Spatiales (LEGOS, CNES/CNRS/IRD/University of Toulouse), 14 av. Edouard Belin, 31400 Toulouse</wicri:regionArea><placeName><settlement type="city">Toulouse</settlement><region type="region" nuts="2">Occitanie (région administrative)</region><region type="old region" nuts="2">Midi-Pyrénées</region></placeName></affiliation></author><author><name sortKey="Rehkamper, Mark" sort="Rehkamper, Mark" uniqKey="Rehkamper M" first="Mark" last="Rehkamper">Mark Rehkamper</name><affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Earth Science and Engineering, Imperial College London, London SW7 2AZ</wicri:regionArea><wicri:noRegion>London SW7 2AZ</wicri:noRegion></affiliation></author><author><name sortKey="Rouxel, Olivier" sort="Rouxel, Olivier" uniqKey="Rouxel O" first="Olivier" last="Rouxel">Olivier Rouxel</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543</wicri:regionArea><placeName><region type="state">Massachusetts</region></placeName></affiliation><affiliation wicri:level="1"><country xml:lang="fr">France</country><wicri:regionArea>IFREMER, Centre de Brest, 29280 Plouzane</wicri:regionArea><wicri:noRegion>29280 Plouzane</wicri:noRegion><wicri:noRegion>29280 Plouzane</wicri:noRegion></affiliation></author><author><name sortKey="Sohrin, Yoshiki" sort="Sohrin, Yoshiki" uniqKey="Sohrin Y" first="Yoshiki" last="Sohrin">Yoshiki Sohrin</name><affiliation wicri:level="4"><country xml:lang="fr">Japon</country><wicri:regionArea>Institute for Chemical Research, Kyoto University, Uji, Kyoto 611‐0011</wicri:regionArea><orgName type="university">Université de Kyoto</orgName><placeName><settlement type="city">Kyoto</settlement><region type="prefecture">Région du Kansai</region></placeName></affiliation></author><author><name sortKey="Stirling, Claudine" sort="Stirling, Claudine" uniqKey="Stirling C" first="Claudine" last="Stirling">Claudine Stirling</name><affiliation wicri:level="1"><country xml:lang="fr">Nouvelle-Zélande</country><wicri:regionArea>Department of Chemistry, University of Otago, Dunedin 9054</wicri:regionArea><wicri:noRegion>Dunedin 9054</wicri:noRegion></affiliation></author><author><name sortKey="Thompson, Claire" sort="Thompson, Claire" uniqKey="Thompson C" first="Claire" last="Thompson">Claire Thompson</name><affiliation wicri:level="1"><country xml:lang="fr">Australie</country><wicri:regionArea>Research School of Earth Sciences, Australian National University</wicri:regionArea><wicri:noRegion>Australian National University</wicri:noRegion></affiliation></author><author><name sortKey="Vance, Derek" sort="Vance, Derek" uniqKey="Vance D" first="Derek" last="Vance">Derek Vance</name><affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>School of Earth Sciences, University of Bristol, Bristol BS8 1RJ</wicri:regionArea><wicri:noRegion>Bristol BS8 1RJ</wicri:noRegion></affiliation></author><author><name sortKey="Xue, Zichen" sort="Xue, Zichen" uniqKey="Xue Z" first="Zichen" last="Xue">Zichen Xue</name><affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Earth Science and Engineering, Imperial College London, London SW7 2AZ</wicri:regionArea><wicri:noRegion>London SW7 2AZ</wicri:noRegion></affiliation></author><author><name sortKey="Zhao, Ye" sort="Zhao, Ye" uniqKey="Zhao Y" first="Ye" last="Zhao">Ye Zhao</name><affiliation wicri:level="1"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>School of Earth Sciences, University of Bristol, Bristol BS8 1RJ</wicri:regionArea><wicri:noRegion>Bristol BS8 1RJ</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Limnology and Oceanography: Methods</title><title level="j" type="alt">LIMNOLOGY AND OCEANOGRAPHY: METHODS</title><idno type="ISSN">1541-5856</idno><idno type="eISSN">1541-5856</idno><imprint><biblScope unit="vol">10</biblScope><biblScope unit="issue">9</biblScope><biblScope unit="page" from="653">653</biblScope><biblScope unit="page" to="665">665</biblScope><biblScope unit="page-count">13</biblScope><date type="published" when="2012-09">2012-09</date></imprint><idno type="ISSN">1541-5856</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1541-5856</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Abouchami</term><term>Acta</term><term>Adkins</term><term>Anal</term><term>Anion</term><term>Boyle</term><term>Cadmium</term><term>Chem</term><term>Coprecipitation</term><term>Coprecipitation method</term><term>Cosmochim</term><term>Deep water</term><term>Double spike</term><term>Earth planet</term><term>Fractionation</term><term>Geochim</term><term>Geoff smith</term><term>Geotraces</term><term>Gpri</term><term>Intercalibration</term><term>Iron isotopes</term><term>Isobaric interferences</term><term>Isotope</term><term>Isotope analysis</term><term>Isotope compositions</term><term>Isotope data</term><term>Isotope fractionation</term><term>Isotope ratios</term><term>Isotopic</term><term>Isotopic composition</term><term>Mainz</term><term>Mass bias</term><term>Minimum amount</term><term>Nist</term><term>Otago</term><term>Permil</term><term>Report data</term><term>Ripperger</term><term>Sample depth</term><term>Seawater</term><term>Seawater samples</term><term>Seth john</term><term>Single analysis</term><term>Spike</term><term>Standard error</term><term>Trace element isotopes</term><term>Trace element isotopes table</term><term>Trace metals</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Abouchami</term><term>Acta</term><term>Adkins</term><term>Anal</term><term>Anion</term><term>Boyle</term><term>Cadmium</term><term>Chem</term><term>Coprecipitation</term><term>Coprecipitation method</term><term>Cosmochim</term><term>Deep water</term><term>Double spike</term><term>Earth planet</term><term>Fractionation</term><term>Geochim</term><term>Geoff smith</term><term>Geotraces</term><term>Gpri</term><term>Intercalibration</term><term>Iron isotopes</term><term>Isobaric interferences</term><term>Isotope</term><term>Isotope analysis</term><term>Isotope compositions</term><term>Isotope data</term><term>Isotope fractionation</term><term>Isotope ratios</term><term>Isotopic</term><term>Isotopic composition</term><term>Mainz</term><term>Mass bias</term><term>Minimum amount</term><term>Nist</term><term>Otago</term><term>Permil</term><term>Report data</term><term>Ripperger</term><term>Sample depth</term><term>Seawater</term><term>Seawater samples</term><term>Seth john</term><term>Single analysis</term><term>Spike</term><term>Standard error</term><term>Trace element isotopes</term><term>Trace element isotopes table</term><term>Trace metals</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Cadmium</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract">We report data on the isotopic composition of cadmium, copper, iron, lead, zinc, and molybdenum at the GEOTRACES IC1 BATS Atlantic intercalibration station. In general, the between lab and within‐lab precisions are adequate to resolve global gradients and vertical gradients at this station for Cd, Fe, Pb, and Zn. Cd and Zn isotopes show clear variations in the upper water column and more subtle variations in the deep water; these variations are attributable, in part, to progressive mass fractionation of isotopes by Rayleigh distillation from biogenic uptake and/or adsorption. Fe isotope variability is attributed to heavier crustal dust and hydrothermal sources and light Fe from reducing sediments. Pb isotope variability results from temporal changes in anthropogenic source isotopic compositions and the relative contributions of U.S. and European Pb sources. Cu and Mo isotope variability is more subtle and close to analytical precision. Although the present situation is adequate for proceeding with GEOTRACES, it should be possible to improve the within‐lab and between‐lab precisions for some of these properties.</div></front></TEI><affiliations><list><country><li>Allemagne</li><li>Australie</li><li>France</li><li>Japon</li><li>Nouvelle-Zélande</li><li>Royaume-Uni</li><li>États-Unis</li></country><region><li>Californie</li><li>Caroline du Sud</li><li>Massachusetts</li><li>Midi-Pyrénées</li><li>Occitanie (région administrative)</li><li>Région du Kansai</li></region><settlement><li>Kyoto</li><li>Toulouse</li></settlement><orgName><li>Université de Kyoto</li></orgName></list><tree><country name="États-Unis"><region name="Massachusetts"><name sortKey="Boyle, Edward A" sort="Boyle, Edward A" uniqKey="Boyle E" first="Edward A." last="Boyle">Edward A. Boyle</name></region><name sortKey="Adkins, Jess F" sort="Adkins, Jess F" uniqKey="Adkins J" first="Jess F." last="Adkins">Jess F. Adkins</name><name sortKey="Boyle, Edward A" sort="Boyle, Edward A" uniqKey="Boyle E" first="Edward A." last="Boyle">Edward A. Boyle</name><name sortKey="Echegoyen Anz, Yolanda" sort="Echegoyen Anz, Yolanda" uniqKey="Echegoyen Anz Y" first="Yolanda" last="Echegoyen-Sanz">Yolanda Echegoyen-Sanz</name><name sortKey="Flegal, A Russell" sort="Flegal, A Russell" uniqKey="Flegal A" first="A. Russell" last="Flegal">A. Russell Flegal</name><name sortKey="Fornace, Kyrstin" sort="Fornace, Kyrstin" uniqKey="Fornace K" first="Kyrstin" last="Fornace">Kyrstin Fornace</name><name sortKey="Gallon, Celine" sort="Gallon, Celine" uniqKey="Gallon C" first="Celine" last="Gallon">Celine Gallon</name><name sortKey="John, Seth" sort="John, Seth" uniqKey="John S" first="Seth" last="John">Seth John</name><name sortKey="John, Seth" sort="John, Seth" uniqKey="John S" first="Seth" last="John">Seth John</name><name sortKey="Rouxel, Olivier" sort="Rouxel, Olivier" uniqKey="Rouxel O" first="Olivier" last="Rouxel">Olivier Rouxel</name></country><country name="Allemagne"><noRegion><name sortKey="Abouchami, Wafa" sort="Abouchami, Wafa" uniqKey="Abouchami W" first="Wafa" last="Abouchami">Wafa Abouchami</name></noRegion><name sortKey="Galer, Steve" sort="Galer, Steve" uniqKey="Galer S" first="Steve" last="Galer">Steve Galer</name></country><country name="Australie"><noRegion><name sortKey="Ellwood, Michael" sort="Ellwood, Michael" uniqKey="Ellwood M" first="Michael" last="Ellwood">Michael Ellwood</name></noRegion><name sortKey="Thompson, Claire" sort="Thompson, Claire" uniqKey="Thompson C" first="Claire" last="Thompson">Claire Thompson</name></country><country name="Nouvelle-Zélande"><noRegion><name sortKey="Gault Ingold, Melanie" sort="Gault Ingold, Melanie" uniqKey="Gault Ingold M" first="Melanie" last="Gault-Ringold">Melanie Gault-Ringold</name></noRegion><name sortKey="Stirling, Claudine" sort="Stirling, Claudine" uniqKey="Stirling C" first="Claudine" last="Stirling">Claudine Stirling</name></country><country name="France"><region name="Occitanie (région administrative)"><name sortKey="Lacan, Francois" sort="Lacan, Francois" uniqKey="Lacan F" first="Francois" last="Lacan">Francois Lacan</name></region><name sortKey="Radic, Amandine" sort="Radic, Amandine" uniqKey="Radic A" first="Amandine" last="Radic">Amandine Radic</name><name sortKey="Rouxel, Olivier" sort="Rouxel, Olivier" uniqKey="Rouxel O" first="Olivier" last="Rouxel">Olivier Rouxel</name></country><country name="Royaume-Uni"><noRegion><name sortKey="Rehkamper, Mark" sort="Rehkamper, Mark" uniqKey="Rehkamper M" first="Mark" last="Rehkamper">Mark Rehkamper</name></noRegion><name sortKey="Vance, Derek" sort="Vance, Derek" uniqKey="Vance D" first="Derek" last="Vance">Derek Vance</name><name sortKey="Xue, Zichen" sort="Xue, Zichen" uniqKey="Xue Z" first="Zichen" last="Xue">Zichen Xue</name><name sortKey="Zhao, Ye" sort="Zhao, Ye" uniqKey="Zhao Y" first="Ye" last="Zhao">Ye Zhao</name></country><country name="Japon"><region name="Région du Kansai"><name sortKey="Sohrin, Yoshiki" sort="Sohrin, Yoshiki" uniqKey="Sohrin Y" first="Yoshiki" last="Sohrin">Yoshiki Sohrin</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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